Anionic polymerization: principles and practical by Henry L. Hsieh, Roderic P. Quirk PDF

By Henry L. Hsieh, Roderic P. Quirk

ISBN-10: 0824795237

ISBN-13: 9780824795238

This paintings introduces the elemental theories and experimental equipment of anionic polymerization in addition to the synthesis, research and features of anionic polymerized items. It information the construction of linear and branched polymers, random and block copolymers, graft and macromonomers, and plenty of different ingredients. The paintings emphasizes the connection among primary ideas and advertisement applications.;College or college bookstores may perhaps buy 5 or extra copies at a unique pupil fee, on hand on request from Marcel Dekker, Inc.

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Extra info for Anionic polymerization: principles and practical applications

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60 electrons for monomeric methyllithium [33]. 23 electronic units for the dimer, tetramer, and hexamer, respectively [34]. , in initiation of anionic polymerization; see Chapters 4 and 6): the less aggregated species, in general, have a somewhat higher degree of ionic character in the carbon-lithium bond. 4 kcal/mol, respectively [34]. However, another recent ab initio calculation study at the restricted Hartree-Fock level concluded that monomeric methyllithium is 88% ionic and that the bonding in oligomers is largely electrostatic and more ionic than in the monomer [35].

26. W. McLean, P. T. Murray, and R. C. Jarnagin, J. Chem. , 69, 2715 (1978). 27. D. Plavsic, D. Srzic, and L. Klasinc, J. Phys. , 90, 2075 (1986). 28. J. L. Atwood, T. Fjeldberg, M. F. Lappert, N. Tuyet Luong-Thi, R. Shakir, and A. J. Thorne, J. Chem. Soc. Chem. , 1163 (1984). 29. R. T. Sanderson, Chemical Periodicity, Reinhold, New York, 1960. 30. A. , J. Organomet. , 156, 1 (1978). 31. A. , J. E. , S. Alexandratos, and J. M. McKelvey, J. Am. Chem. , 98, 4778 (1976). 32. J. B. Collins and A. , J.

8e. 60 electrons for monomeric methyllithium [33]. 23 electronic units for the dimer, tetramer, and hexamer, respectively [34]. , in initiation of anionic polymerization; see Chapters 4 and 6): the less aggregated species, in general, have a somewhat higher degree of ionic character in the carbon-lithium bond. 4 kcal/mol, respectively [34]. However, another recent ab initio calculation study at the restricted Hartree-Fock level concluded that monomeric methyllithium is 88% ionic and that the bonding in oligomers is largely electrostatic and more ionic than in the monomer [35].

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Anionic polymerization: principles and practical applications by Henry L. Hsieh, Roderic P. Quirk


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