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ISBN-10: 3527328858

ISBN-13: 9783527328857

ISBN-10: 3527644113

ISBN-13: 9783527644117

Bioelectrochemistry is a quick growing to be box on the interface among electrochemistry and different sciences reminiscent of biochemistry, analytical chemistry and medicinal chemistry. within the fresh years, the equipment and the knowledge of the basics have obvious major development, which has ended in speedy improvement within the field.

right here, the professional editors have conscientiously chosen contributions to top replicate the most recent advancements during this sizzling and swiftly becoming interdisciplinary subject. The ensuing very good and well timed assessment of this multifaceted box covers fresh methodological advances, in addition to more than a few new functions for analytical detection, drug screening, tumor remedy, and for power conversion in biofuel cells.

This booklet is a must have for all Electrochemists, Biochemists, Analytical Chemists, and Medicinal Chemists.

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Extra info for Advances in Electrochemical Science and Engineering: Bioelectrochemistry, Volume 13

Example text

6 (mobile or immobilized) mediators and/or conducting polymers can also be employed to shuttle electrons between a redox enzyme and an electrode surface [11, 12, 16, 20, 21, 24, 25, 28, 270–273]. 6). Efficient ET throughout the entire sensing layer is envisaged in order to avoid only the enzyme layer in close vicinity to the electrode surface contributing to the overall current signal. For many applications, soluble mediators are not suitable. Thus, redox hydrogels (hydrogels covalently modified with a redox-active mediator) are increasingly being used for reagentless biosensor structures and more recently also for biofuel cells.

For several applications, however, there is a need for online analysis in real time, such as quality control in the food or drug industries or metabolite monitoring at the bedside or during surgery. 9 Areas of application for biosensors. 2 Criteria for “Good” Biosensor Research a single-use device differ from those for multi-analysis and continuous monitoring and have to be taken into account when considering overall biosensor architecture. 2 Criteria for “Good” Biosensor Research It is obvious that science does not always lead to ground-breaking advancements that are worth publishing.

Biofuel cells presently reach a power output in the range of about 10−6 to 10−3 W cm−2. Practical conventional fuel cells operate in the range of about 1 to 108 W cm−2 [303]. Taking the calculations from Barton and coworkers into consideration [70], in which, as mentioned above, the theoretical current density of a monolayer was estimated to be about 80 μA cm−2, one would require thousands of layers to obtain a current density above 10 mA cm−2. To summarize, the advent of redox-relay modified polymers, such as redox hydrogels, conducting polymers, or EDPs, enabled the development of biosensors that even made it to commercial applications such as implantable glucose sensors.

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Advances in Electrochemical Science and Engineering: Bioelectrochemistry, Volume 13


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